Ru-catalyzed olefin metathesis has been successfully applied to the synthesis of biscardanol derivatives and cardanol-based porphyrins. Using Hoveyda–Grubbs catalyst (C627), the reactions were performed with various cardanol derivatives (2, 5, 7, and 9) to make novel biscardanol derivatives. With the use of the second-generation Grubbs catalyst (C848) and Ti(OiPr)4, the ring-closing metathesis of cardanol- based porphyrin 11 was carried out to afford cyclic cardanol-based porphyrin derivative 12.
An Efficient Route to Biscardanol Derivatives and Cardanol-Based Porphyrins via Olefin Metathesis
MELE, Giuseppe Agostino;MARTINA, FRANCESCA;MARGAPOTI, Eleonora;VASAPOLLO, Giuseppe;
2006-01-01
Abstract
Ru-catalyzed olefin metathesis has been successfully applied to the synthesis of biscardanol derivatives and cardanol-based porphyrins. Using Hoveyda–Grubbs catalyst (C627), the reactions were performed with various cardanol derivatives (2, 5, 7, and 9) to make novel biscardanol derivatives. With the use of the second-generation Grubbs catalyst (C848) and Ti(OiPr)4, the ring-closing metathesis of cardanol- based porphyrin 11 was carried out to afford cyclic cardanol-based porphyrin derivative 12.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
