Different scanning force microscopy (SFM) techniques were employed to investigate the structure and composition of the fundamental crystal faces of prototype halogen-bonded co-crystals of long-chain perfluorocarbons. These crystals were found to show surfaces with well-defined ledges formed by intersecting crystal planes having different chemical compositions with the perfluorocarbons (PFCs) covering the largest area of the crystal as a reminiscence of the strong segregation observed in the bulk crystal structure.
SFM study of the surface of halogen-bonded hybrid co-crystals containing long-chain perfluorocarbons
MARUCCIO, Giuseppe;ARIMA, VALENTINA;CINGOLANI, Roberto;RINALDI, Rosaria;
2009-01-01
Abstract
Different scanning force microscopy (SFM) techniques were employed to investigate the structure and composition of the fundamental crystal faces of prototype halogen-bonded co-crystals of long-chain perfluorocarbons. These crystals were found to show surfaces with well-defined ledges formed by intersecting crystal planes having different chemical compositions with the perfluorocarbons (PFCs) covering the largest area of the crystal as a reminiscence of the strong segregation observed in the bulk crystal structure.File in questo prodotto:
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