A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbonylation of allylic and benzylic halides is described. The methodology has been applied to primary, secondary, and tertiary alcohols as well as to phenol derivatives. The O-protection of some biologically relevant molecules is also reported.
One-Pot Ester Synthesis from Allyl an Benzyl Halides and Alcohols by Palladium-Catalyzed Carbonylation.
S. PERRONE;Salomone, Antonio;TROISI, Luigino
2012-01-01
Abstract
A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbonylation of allylic and benzylic halides is described. The methodology has been applied to primary, secondary, and tertiary alcohols as well as to phenol derivatives. The O-protection of some biologically relevant molecules is also reported.File in questo prodotto:
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