Over the last few years, graphene oxide (GO) has stood out as an ideal carbon-filler to dope polymer matrix, specifically conductive polymers. This paper investigates the possibility of producing ternary nanocomposites based on a conductive polymer poly(3,4 ethylene dioxythiophene) polystyrene sulfonate (PEDOT:PSS), doped with graphene oxide (GO) and is additivated with a green dispersing and reducing agent (ascorbic acid). Three-component inks have been developed and their rheological and surface tension properties are studied to evaluate their filmability. Subsequently, through the drop-casting technique, thin films of the inks are produced, and their electrochemical behavior is deeply analyzed via cyclic voltammetry tests (CV). Particularly, PEDOT:PSS/GO/AA ink shows a higher specific capacitance (Csp) up to 29.84 mF cm−2 than pristine PEDOT:PSS, suggesting that this ink can be used as an electrode material for supercapacitor devices.

Novel Supercapacitor Based on Pedot:PSS/Graphene Oxide Nanocomposite

Greco, Giuseppe;Giuri, Antonella;Bagheri, Sonia;Mele, Claudio;Corcione, Carola Esposito
2024-01-01

Abstract

Over the last few years, graphene oxide (GO) has stood out as an ideal carbon-filler to dope polymer matrix, specifically conductive polymers. This paper investigates the possibility of producing ternary nanocomposites based on a conductive polymer poly(3,4 ethylene dioxythiophene) polystyrene sulfonate (PEDOT:PSS), doped with graphene oxide (GO) and is additivated with a green dispersing and reducing agent (ascorbic acid). Three-component inks have been developed and their rheological and surface tension properties are studied to evaluate their filmability. Subsequently, through the drop-casting technique, thin films of the inks are produced, and their electrochemical behavior is deeply analyzed via cyclic voltammetry tests (CV). Particularly, PEDOT:PSS/GO/AA ink shows a higher specific capacitance (Csp) up to 29.84 mF cm−2 than pristine PEDOT:PSS, suggesting that this ink can be used as an electrode material for supercapacitor devices.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11587/530966
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