Phase Change Materials in Lime-Based Mortars for the Energy Efficiency of Historic Buildings: State-of-the-Art and Prospects

Historic buildings represent a substantial share of the European building stock. However, their energy retrofit is heavily restricted by conservation principles that often exclude conventional insulation systems. In this context, phase change materials (PCMs) incorporated into lime-based mortars have emerged as a potentially compatible solution, combining latent heat storage capacity with the compatibility traditionally associated with aerial lime, the binder of reference in conservation practice. In some cases, natural hydraulic lime and hydrated lime are also used in heritage conservation applications. The aim of this study, therefore, is to provide a systematic review of peer-reviewed articles published between 2010 and 2026 that illustrate the use of PCM-containing lime mortars applied in historic buildings. The analysis examines PCM types, incorporation methods, thermal and mechanical behavior, durability, and compatibility with conservation requirements. The reviewed studies demonstrate that the incorporation of PCM generally reduces internal thermal fluctuations in buildings along with capillary water absorption. Durability investigations indicate improved resistance to freeze–thaw cycles and salt crystallization of mortars containing such PCMs. However, durability was investigated in less than 20% of the studies reviewed. Lime mortars show a consistent reduction in compressive strength as the PCM content increases; on the other hand, hydrated lime mortars can also offer increases in strength. Although the reviewed studies focused on applications in historic buildings, the reversibility of the intervention and its compatibility with historic substrates was not assessed according to the standards required for the conservation of cultural heritage. This gap represents the main limitation of the research conducted.